Topochemical polymerization of phenylacetylene macrocycles: a new strategy for the preparation of organic nanorods.
نویسندگان
چکیده
Soluble organic nanorods were prepared from phenylacetylene macrocycles using the topochemical polymerization of butadiyne moieties placed both inside and outside the macrocycles' skeletons. Macrocycles containing amide groups were self-assembled in a columnar fashion through the formation of an organogel in ethyl acetate. Upon irradiation with UV light, the Raman signals associated with butadiyne units completely vanished, indicating the creation of covalently linked nanorods.
منابع مشابه
Improving the reactivity of phenylacetylene macrocycles toward topochemical polymerization by side chains modification
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 135 1 شماره
صفحات -
تاریخ انتشار 2013